Activity and Decay Constant in Radioactive Decay
Introduction
Radioactive decay is a fundamental concept in nuclear physics, pivotal for understanding the stability and transformation of atomic nuclei. In the context of the AS & A Level Physics curriculum (9702), defining activity and the decay constant provides essential insights into the behavior of radioactive substances. Mastery of the equation $A = \lambda N$ is crucial for students to analyze and predict the rate of decay in various nuclear processes.
Key Concepts
Definition of Activity
Activity ($A$) in radioactive decay refers to the number of disintegrations per unit time occurring in a radioactive sample. It quantifies the rate at which a radioactive isotope undergoes decay, emitting particles or radiation. The SI unit of activity is the becquerel (Bq), where $1\, \text{Bq} = 1\, \text{disintegration per second}$. Historically, the curie (Ci) was used, where $1\, \text{Ci} = 3.7 \times 10^{10}\, \text{Bq}$, but the becquerel is the preferred unit in the International System of Units (SI).
Decay Constant ($\lambda$)
The decay constant ($\lambda$) is a probabilistic measure that represents the likelihood of a single nucleus decaying per unit time. It is intrinsic to each radioactive isotope and is independent of the sample size. The decay constant is measured in inverse seconds ($\text{s}^{-1}$) and is related to the half-life ($T_{1/2}$) of the isotope by the equation:
$$\lambda = \frac{\ln 2}{T_{1/2}}$$
A higher decay constant indicates a more unstable nucleus with a shorter half-life, while a lower decay constant signifies greater stability and a longer half-life.
Number of Unstable Nuclei ($N$)
$N$ denotes the total number of radioactive nuclei present in a sample at a given time. It is a crucial factor in determining the activity of the sample. As radioactive decay progresses, $N$ decreases exponentially, leading to a corresponding decrease in activity.
Relationship Among Activity, Decay Constant, and Number of Nuclei
The fundamental relationship among activity ($A$), decay constant ($\lambda$), and the number of unstable nuclei ($N$) is expressed by the equation:
$$A = \lambda N$$
This equation highlights that the activity of a radioactive sample is directly proportional to both the decay constant and the number of radioactive nuclei present. Understanding this relationship allows for the prediction of decay rates and the calculation of remaining radioactive material over time.
Exponential Decay Law
Radioactive decay follows an exponential law, where the number of undecayed nuclei decreases exponentially with time. The mathematical representation is:
$$N(t) = N_0 e^{-\lambda t}$$
where:
- $N(t)$ is the number of undecayed nuclei at time $t$.
- $N_0$ is the initial number of nuclei at time $t=0$.
- $\lambda$ is the decay constant.
- $e$ is the base of the natural logarithm.
This equation underscores the probabilistic nature of radioactive decay, indicating that a constant fraction of the remaining nuclei decay over equal time intervals.
Half-Life ($T_{1/2}$)
The half-life of a radioactive isotope is the time required for half of the radioactive nuclei in a sample to decay. It is related to the decay constant by:
$$T_{1/2} = \frac{\ln 2}{\lambda}$$
Half-life is a convenient measure for expressing the rate of decay, especially in practical applications such as radiometric dating and nuclear medicine.
Calculating Activity
To calculate the activity of a radioactive sample, students can use the equation:
$$A = \lambda N$$
For example, if a sample contains $N = 1.5 \times 10^{20}$ undecayed nuclei with a decay constant $\lambda = 2.5 \times 10^{-3}\, \text{s}^{-1}$, the activity is:
$$A = (2.5 \times 10^{-3}\, \text{s}^{-1})(1.5 \times 10^{20}) = 3.75 \times 10^{17}\, \text{Bq}$$
This high activity indicates a very active radioactive sample.
Practical Implications
Understanding activity and decay constants is essential in various applications:
- Medical Imaging: Radioactive tracers with suitable decay constants are used in PET scans.
- Radiometric Dating: Determining the age of archaeological finds relies on decay constants and activity measurements.
- Nuclear Power: Managing radioactive waste involves understanding decay rates to ensure safety over time.
These applications demonstrate the real-world relevance of mastering these key concepts in radioactive decay.
Advanced Concepts
Mathematical Derivation of the Decay Equation
Starting from the probability of decay, the differential equation governing radioactive decay is:
$$\frac{dN}{dt} = -\lambda N$$
Solving this first-order linear differential equation involves separating variables and integrating:
$$\int \frac{1}{N} dN = -\lambda \int dt$$
$$\ln N = -\lambda t + C$$
Exponentiating both sides gives:
$$N(t) = N_0 e^{-\lambda t}$$
where $N_0$ is the number of nuclei at $t=0$, derived from the initial condition.
Integrated Activity Over Time
The activity as a function of time is obtained by differentiating the number of undecayed nuclei:
$$A(t) = \lambda N(t) = \lambda N_0 e^{-\lambda t}$$
This demonstrates that activity decreases exponentially over time, mirroring the decrease in the number of undecayed nuclei.
Decay Chains and Secular Equilibrium
In decay chains involving multiple radioactive isotopes, the activity of parent and daughter nuclei can reach a state of secular equilibrium, where the activity of the daughter equals that of the parent. This occurs when the half-life of the parent is much longer than that of the daughter, allowing the system to stabilize with constant activities.
Interdisciplinary Connections
The principles of radioactive decay and activity have profound implications across various scientific disciplines:
- Chemistry: Radiochemical methods rely on understanding decay constants for isotope separation.
- Geology: Radiometric dating techniques utilize decay rates to determine the age of rocks and minerals.
- Environmental Science: Tracking radioactive pollutants involves monitoring their decay and activity levels.
- Medicine: Radioisotopes are used in both diagnostic imaging and cancer treatment, necessitating precise knowledge of their decay properties.
These connections highlight the versatility and importance of radioactive decay principles beyond the realm of physics.
Complex Problem-Solving: Multi-Step Decay Calculations
Consider a sample containing two radioactive isotopes, A and B, where A decays into B, and B is stable. The decay constants are $\lambda_A$ and $\lambda_B$, respectively. To find the number of atoms of B at time $t$, we use the Bateman equations:
$$N_B(t) = \frac{\lambda_A}{\lambda_B - \lambda_A} N_0 \left(e^{-\lambda_A t} - e^{-\lambda_B t}\right)$$
This formula accounts for the production of B from the decay of A and its subsequent decay.
Half-Life Ratios and Age Determination
In radiometric dating, the ratio of parent to daughter isotopes and their respective half-lives allows for the calculation of the age of a sample. For example, using carbon-14 dating:
$$\text{Age} = \frac{\ln\left(\frac{N_0}{N}\right)}{\lambda}$$
where $N_0$ is the original quantity of carbon-14, and $N$ is the remaining quantity.
Nuclear Medicine Applications
Radioactive isotopes with specific decay constants are employed in diagnostic imaging and therapeutic procedures. Understanding activity ensures appropriate dosage and timing for effective treatment while minimizing exposure:
- PET Scans: Use isotopes like fluorine-18, which have suitable decay constants for imaging.
- Radiotherapy: Utilize isotopes like iodine-131 for targeting cancer cells.
Precise calculations of activity and decay constants are critical for the safe and effective use of these technologies.
Comparison Table
Aspect |
Activity (A) |
Decay Constant ($\lambda$) |
Definition |
Number of disintegrations per unit time. |
Probability of decay per nucleus per unit time. |
Units |
Becquerels (Bq) |
Inverse seconds ($\text{s}^{-1}$) |
Dependence |
A ∝ N |
Intrinsic property of the isotope. |
Role in $A = \lambda N$ |
Represents the activity. |
Connects activity to the number of nuclei. |
Relation to Half-Life |
Decreases as N decreases over time. |
Calculates half-life via $\lambda = \frac{\ln 2}{T_{1/2}}$. |
Summary and Key Takeaways
- Activity ($A$) quantifies the decay rate of a radioactive sample.
- Decay Constant ($\lambda$) indicates the probability of decay per nucleus per unit time.
- The fundamental equation $A = \lambda N$ links activity, decay constant, and the number of nuclei.
- Understanding these concepts is essential for applications in medicine, geology, and environmental science.
- Advanced studies involve decay chains, equilibrium states, and interdisciplinary applications.