The concept of the amount of substance is fundamental in physics and chemistry, serving as a bridge between the macroscopic and microscopic worlds. Recognized as an SI base quantity, the mole ($\text{mol}$) provides a standardized unit for measuring the number of elementary entities, ensuring consistency in scientific calculations and experiments. This understanding is crucial for students studying Physics - 9702 at the AS & A Level, as it underpins many advanced topics in physical chemistry and material science.

Key Concepts

Definition of Amount of Substance

The amount of substance, quantified in moles ($\text{mol}$), is an SI base quantity representing the number of elementary entities, such as atoms, molecules, ions, or electrons, in a given sample. One mole corresponds to exactly $6.02214076 \times 10^{23}$ entities, a value known as Avogadro's number ($N_A$).

SI Base Quantity

In the International System of Units (SI), base quantities are fundamental physical quantities that cannot be derived from other quantities. The amount of substance is one of the seven SI base quantities, alongside length, mass, time, electric current, thermodynamic temperature, and luminous intensity. Recognizing the amount of substance as a base quantity emphasizes its fundamental role in scientific measurements and calculations.

Unit of Amount of Substance: The Mole

The mole ($\text{mol}$) is the SI unit for amount of substance. Defined by the fixed numerical value of Avogadro's number, the mole provides a bridge between the atomic scale and the macroscopic scale. This allows chemists and physicists to count particles by weighing macroscopic amounts of material.

Avogadro's Number

Avogadro's number ($N_A = 6.02214076 \times 10^{23} \, \text{mol}^{-1}$) is a fundamental constant that defines the number of elementary entities in one mole of substance. It is critical for converting between the mass of a substance and the number of atoms or molecules it contains.

Molar Mass

The molar mass is the mass of one mole of a substance, typically expressed in grams per mole ($\text{g/mol}$). It relates the mass of a sample to the number of moles, allowing for calculations involving mass, number of particles, and volume under specific conditions.

Relationship Between Mass, Moles, and Molar Mass

The relationship between mass ($m$), amount of substance ($n$), and molar mass ($M$) is given by the equation:

$$ m = n \times M $$

This formula is fundamental in stoichiometry, enabling the calculation of the amount of reactants and products in chemical reactions.

Converting Between Moles and Number of Entities

To determine the number of entities ($N$) in a sample, the following relationship can be used:

$$ N = n \times N_A $$

Conversely, the number of moles can be calculated by:

$$ n = \frac{N}{N_A} $$

These conversions are essential for translating between macroscopic measurements and atomic-scale quantities.

Molar Volume of Gases

At standard temperature and pressure (STP), one mole of an ideal gas occupies a volume of $22.414 \, \text{L}$. This concept, known as molar volume, enables the prediction of gas behavior under varying conditions using the Ideal Gas Law:

$$ PV = nRT $$

Where $P$ is pressure, $V$ is volume, $R$ is the ideal gas constant, and $T$ is temperature.

Applications in Chemical Reactions

The mole concept is indispensable in balancing chemical equations and calculating reactant and product quantities. By ensuring the conservation of mass and number of particles, the mole allows for precise stoichiometric calculations, which are vital for laboratory experiments and industrial processes.

Significance in Material Science

Understanding the amount of substance is crucial in material science for determining material properties, such as density, molar conductivity, and reaction kinetics. It enables the scaling of laboratory results to industrial applications, ensuring the efficient production of materials.

Quantitative Analysis

In quantitative analysis, the mole is used to determine the concentration of solutions, perform titrations, and analyze reaction yields. It facilitates the precise measurement and manipulation of substances in analytical chemistry.

Thermodynamic Calculations

The mole plays a key role in thermodynamics, particularly in calculations involving enthalpy, entropy, and Gibbs free energy. It allows for the quantification of energy changes during chemical reactions and phase transitions.

Electrochemistry

In electrochemistry, the mole is used to calculate the amount of charge transferred during redox reactions. Faraday's laws of electrolysis use the mole to relate electrical energy to chemical change.

Biochemical Applications

The mole concept extends to biochemical processes, enabling the quantification of enzymes, substrates, and biological molecules in reactions. It is essential for understanding metabolic pathways and molecular biology.

Advanced Concepts

Derivation of Avogadro's Number

Avogadro's number is derived from experimental measurements and theoretical calculations. Historically, it was determined through methods such as X-ray diffraction, electron microscopy, and coulometry. Modern determinations involve the measurement of the charge of a mole of electrons and the Planck constant:

$$ N_A = \frac{M_u \cdot N_A \cdot R}{F} $$

Where $M_u$ is the molar mass constant, $R$ is the gas constant, and $F$ is the Faraday constant.

The Ideal Gas Law and the Mole

The Ideal Gas Law, $PV = nRT$, integrates the mole to relate macroscopic gas properties. By manipulating this equation, students can derive relationships between temperature, pressure, and volume, emphasizing the mole's role in bridging microscopic particle behavior with observable gas properties.

Stoichiometric Calculations in Complex Reactions

Advanced stoichiometry involves multiple reactants and products, requiring the use of the mole concept to calculate limiting reagents, percent yields, and reaction efficiencies. These calculations often involve solving systems of equations and applying mole ratios derived from balanced chemical equations.

Intermolecular Forces and Molar Mass

The molar mass influences the physical properties of substances, such as boiling points, melting points, and vapor pressures. Understanding these relationships requires knowledge of intermolecular forces and how they vary with molecular size and structure.

Extensions to Non-ideal Gases

While the Ideal Gas Law provides a foundational understanding, real gases exhibit non-ideal behavior under high pressure or low temperature. The Van der Waals equation modifies the Ideal Gas Law to account for intermolecular forces and finite molecular sizes:

$$ \left(P + \frac{a n^2}{V^2}\right)(V - nb) = nRT $$

Here, $a$ and $b$ are empirical constants specific to each gas, highlighting the mole's role in more accurate gas behavior modeling.

Quantum Chemistry and the Mole

In quantum chemistry, the mole concept ties macroscopic observations to quantum-scale phenomena. Calculations involving electron configurations, molecular orbitals, and reaction mechanisms use the mole to quantify the number of entities participating in interactions.

Isotopic Abundance and Molar Mass Calculations

The natural abundance of isotopes affects the molar mass of elements. Advanced calculations involve weighted averages based on isotopic composition, which is essential for precise stoichiometric and thermodynamic computations.

Coulomb’s Law and Electrochemical Calculations

Coulomb’s Law relates the amount of substance to electric charge in electrochemical cells. Understanding the relationship between moles, charge, and energy is critical for designing batteries and understanding corrosion processes.

Biochemical Stoichiometry

Biological systems often involve complex stoichiometric relationships. Advanced studies include metabolic pathways, enzyme kinetics, and molecular biology, where the mole is used to quantify reactants and products in biochemical reactions.

Entropy and the Mole

Entropy, a measure of disorder, is influenced by the number of ways particles can be arranged. The mole allows for calculations of entropy changes in reactions, linking microscopic particle behavior to macroscopic thermodynamic properties.

Molarity and Solution Chemistry

Molarity, the concentration of a solution expressed in moles per liter, is fundamental in solution chemistry. Advanced concepts include titration curves, buffer solutions, and solubility equilibria, all of which rely on precise molar calculations.

Dimensional Analysis and the Mole

Dimensional analysis uses the mole to ensure the consistency of units in equations and calculations. It is a critical skill in validating complex chemical and physical computations.

Rate Laws and Reaction Mechanisms

In kinetics, the mole is used to express the concentration of reactants in rate laws. Understanding how reaction rates depend on molar concentrations is essential for elucidating reaction mechanisms and designing chemical reactors.

Thermochemistry and Energy Calculations

Thermochemical equations use the mole to quantify energy changes in chemical reactions. Calculations involving enthalpy, entropy, and Gibbs free energy require the mole to relate energy changes to the amount of reactants and products.

Interdisciplinary Applications: Engineering and Environmental Science

The mole concept extends to engineering disciplines, such as chemical engineering, where it is used in process design and optimization. In environmental science, the mole is essential for calculating pollutant concentrations and understanding environmental impact.

Comparison Table

Aspect	Base Quantity	Derived Quantity
Definition	Fundamental physical quantity	Calculated from base quantities
Unit	Mole ($\text{mol}$)	Depends on derived quantity (e.g., $\text{m}^3$, $\text{J}$)
Role in SI	One of the seven SI base quantities	Derived from combinations of base quantities
Examples	Amount of substance	Density, velocity, force
Usage	Counting entities in a sample	Describing physical properties and phenomena

Summary and Key Takeaways

The amount of substance is a fundamental SI base quantity measured in moles.
One mole equals $6.02214076 \times 10^{23}$ entities, known as Avogadro's number.
The mole bridges the gap between microscopic particles and macroscopic measurements.
Understanding the mole is essential for stoichiometry, thermodynamics, and various scientific applications.
Advanced concepts include derivations of Avogadro's number, real gas behavior, and interdisciplinary applications.

Examiner Tip

Tips

Remember the phrase "Mole Bridges Scales" to recall that the mole connects microscopic particles to macroscopic quantities. Use dimensional analysis to systematically convert between mass, moles, and number of entities. Practice balancing chemical equations to strengthen your understanding of stoichiometric relationships for exam success.

Did You Know

Did you know that the concept of the mole was first introduced by the French chemist Jean-Baptiste Perrin in the early 20th century? Additionally, the mole allows scientists to translate between atomic-scale particles and everyday quantities, making complex chemical reactions understandable and manageable in practical terms.

Common Mistakes

A common mistake students make is confusing the number of moles with the number of particles. For example, saying 1 mole of atoms is 1 atom instead of $6.022 \times 10^{23}$ atoms is incorrect. Another mistake is neglecting to use the correct molar mass when converting between mass and moles, leading to calculation errors.

FAQ

What is the definition of a mole?

A mole is the SI unit for the amount of substance, defined as containing exactly $6.02214076 \times 10^{23}$ elementary entities, such as atoms or molecules.

How is Avogadro's number used in calculations?

Avogadro's number allows for the conversion between the number of particles and the number of moles, enabling calculations involving mass, volume, and the number of entities in a sample.

What is molar mass and why is it important?

Molar mass is the mass of one mole of a substance, expressed in grams per mole. It is important for converting between the mass of a substance and the number of moles, facilitating stoichiometric calculations.

How do you convert grams to moles?

To convert grams to moles, divide the mass of the substance by its molar mass using the formula $n = \frac{m}{M}$, where $n$ is the number of moles, $m$ is the mass, and $M$ is the molar mass.

Why is the mole considered an SI base quantity?

The mole is considered an SI base quantity because it represents a fundamental way to quantify the amount of substance, linking the microscopic world of atoms and molecules to macroscopic measurements.

1. Capacitance

1.1 Energy Stored in a Capacitor

1.1.1 Determine electric potential energy stored in a capacitor from the area under the potential–charge g

1.1.2 Recall and use W = ½QV = ½CV²

1.2 Discharging a Capacitor

1.2.1 Analyze graphs of potential difference, charge, and current during capacitor discharge

1.2.2 Recall and use τ = RC for the time constant during discharge

1.2.3 Use equations of the form x = x₀e^(-t / RC) for current, charge, or potential during discharge

1.3 Capacitors and Capacitance

1.3.1 Define capacitance for isolated spherical conductors and parallel plate capacitors

1.3.2 Recall and use C = Q / V

1.3.3 Derive formulae for combined capacitance of capacitors in series and parallel

1.3.4 Use capacitance formulae for capacitors in series and parallel

2. Nuclear Physics

2.1 Mass Defect and Nuclear Binding Energy

2.1.1 Sketch the variation of binding energy per nucleon with nucleon number

2.1.2 Explain nuclear fusion and nuclear fission

2.1.3 Calculate the energy released in nuclear reactions using E = c²∆m

2.1.4 Understand the equivalence between energy and mass (E = mc²)

2.1.5 Define and use the terms mass defect and binding energy

2.2 Radioactive Decay

2.2.1 Understand that fluctuations in count rate provide evidence for random decay

2.2.2 Understand that radioactive decay is spontaneous and random

2.2.3 Define activity and decay constant, and recall A = λN

2.2.4 Define half-life

2.2.5 Use λ = 0.693 / t₁/₂ for the half-life relationship

2.2.6 Understand exponential decay and use the relationship x = x₀e^(-λt)

3. Kinematics

3.1 Equations of Motion

3.1.1 Define and use distance, displacement, speed, velocity, acceleration

3.1.2 Use graphical methods to represent motion

3.1.3 Determine displacement from velocity–time graph

3.1.4 Determine velocity using gradient of displacement–time graph

3.1.5 Determine acceleration using gradient of velocity–time graph

3.1.6 Derive equations for uniformly accelerated motion

3.1.7 Solve problems of uniformly accelerated motion

3.1.8 Describe experiment to determine acceleration due to gravity

3.1.9 Explain motion with uniform velocity and perpendicular acceleration

4. Deformation of Solids

4.1 Stress and Strain

4.1.1 Understand and use the terms load, extension, compression, and limit of proportionality

4.1.2 Recall and use Hooke’s law

4.1.3 Recall and use the formula for spring constant k = F / x

4.1.4 Define and use terms stress, strain, and Young's modulus

4.1.5 Describe an experiment to determine Young’s modulus

4.1.6 Understand deformation caused by tensile or compressive forces

4.2 Elastic and Plastic Behaviour

4.2.1 Understand elastic and plastic deformation and elastic limit

4.2.2 Understand area under the force–extension graph as work done

4.2.3 Calculate elastic potential energy using EP = ½kx²

5. Gravitational Fields

5.1 Gravitational Field of a Point Mass

5.1.1 Understand that g is approximately constant for small height changes near Earth's surface

5.1.2 Recall and use g = GM / r²

5.1.3 Derive and use g = GM / r² for gravitational field strength

5.2 Gravitational Potential

5.2.1 Define gravitational potential as work done per unit mass in bringing a test mass from infinity

5.2.2 Use ϕ = -GM / r for gravitational potential due to a point mass

5.2.3 Use EP = -GMm / r for gravitational potential energy between two point masses

5.3 Gravitational Field

5.3.1 Define gravitational field as force per unit mass

5.3.2 Represent a gravitational field using field lines

5.4 Gravitational Force Between Point Masses

5.4.1 For point outside uniform sphere, treat mass as a point mass at its center

5.4.2 Analyze circular orbits in gravitational fields

5.4.3 Recall and use Newton's law of gravitation F = Gm₁m₂ / r²

6. Electricity

6.1 Resistance and Resistivity

6.1.1 Understand that the resistance of a thermistor decreases as temperature increases

6.1.2 Define resistance and recall and use V = IR

6.1.3 Sketch I–V characteristics for metallic conductor, semiconductor diode, and filament lamp

6.1.4 Explain that the resistance of a filament lamp increases as current increases

6.1.5 State Ohm’s law and recall and use R = ρL / A

6.1.6 Understand that the resistance of an LDR decreases as light intensity increases

6.2 Electric Current

6.2.1 Understand that an electric current is a flow of charge carriers

6.2.2 Understand that the charge on charge carriers is quantised

6.2.3 Recall and use Q = It

6.2.4 Use I = Anvq for current-carrying conductors

6.3 Potential Difference and Power

6.3.1 Define potential difference as energy transferred per unit charge

6.3.2 Recall and use V = W / Q

6.3.3 Recall and use P = VI, P = I²R, P = V² / R

7. D.C. Circuits

7.1 Practical Circuits

7.1.1 Recall and use the circuit symbols in the syllabus

7.1.2 Draw and interpret circuit diagrams using circuit symbols

7.1.3 Define electromotive force (e.m.f.) of a source as energy transferred per unit charge

7.1.4 Distinguish between e.m.f. and potential difference (p.d.)

7.1.5 Understand the effects of internal resistance on terminal potential difference

7.2 Kirchhoff’s Laws

7.2.1 Recall Kirchhoff’s first law: conservation of charge

7.2.2 Recall Kirchhoff’s second law: conservation of energy

7.2.3 Derive the formula for combined resistance of resistors in series using Kirchhoff’s laws

7.2.4 Use the formula for combined resistance of resistors in series

7.2.5 Derive the formula for combined resistance of resistors in parallel using Kirchhoff’s laws

7.2.6 Use the formula for combined resistance of resistors in parallel

7.2.7 Use Kirchhoff’s laws to solve simple circuit problems

7.3 Potential Dividers

7.3.1 Understand the principle of a potential divider circuit

7.3.2 Recall and use the principle of the potentiometer for comparing potential differences

7.3.3 Understand the use of a galvanometer in null methods

7.3.4 Explain the use of thermistors and LDRs in potential dividers to provide a potential dependent on te

8. Thermal Equilibrium

8.1 Thermal Energy Transfer

8.1.1 Understand that thermal energy transfers from higher to lower temperature

8.1.2 Understand that regions of equal temperature are in thermal equilibrium

9. Temperature Scales

9.1 Temperature Measurement

9.1.1 Understand physical properties that vary with temperature (e.g., density, gas volume, resistance)

9.1.2 Convert temperatures between Kelvin and Celsius, and recall T(K) = θ(°C) + 273.15

10. Magnetic Fields

10.1 Concept of a Magnetic Field

10.1.1 Understand that a magnetic field is a field of force produced by moving charges or permanent magnets

10.1.2 Represent a magnetic field using field lines

10.2 Force on a Current-Carrying Conductor

10.2.1 Understand that a force acts on a current-carrying conductor in a magnetic field

10.2.2 Recall and use F = BIL sin θ for the force on a current-carrying conductor in a magnetic field

10.2.3 Define magnetic flux density as the force per unit current per unit length on a wire at right angles

10.3 Force on a Moving Charge

10.3.1 Determine the direction of the force on a charge moving in a magnetic field

10.3.2 Recall and use F = BQv sin θ for the force on a moving charge in a magnetic field

10.3.3 Understand the origin of the Hall voltage and use the expression VH = BI / (ntq) for the Hall voltag

10.3.4 Understand the use of a Hall probe to measure magnetic flux density

10.4 Magnetic Fields Due to Currents

10.4.1 Sketch magnetic field patterns due to currents in a straight wire, flat coil, and solenoid

10.4.2 Understand that magnetic field in a solenoid is increased by a ferrous core

10.4.3 Explain the origin of forces between current-carrying conductors and determine the direction of the

10.5 Electromagnetic Induction

10.5.1 Define magnetic flux as the product of magnetic flux density and area perpendicular to flux directio

10.5.2 Recall and use Φ = BA for magnetic flux

10.5.3 Understand and use the concept of magnetic flux linkage

10.5.4 Explain experiments that show changing magnetic flux induces an e.m.f.

10.5.5 Recall and use Faraday’s and Lenz’s laws of electromagnetic induction

11. Specific Heat Capacity and Latent Heat

11.1 Specific Heat Capacity

11.1.1 Define and use specific heat capacity

11.2 Latent Heat

11.2.1 Define and use specific latent heat; distinguish between fusion and vaporisation

12. Dynamics

12.1 Momentum and Newton’s Laws of Motion

12.1.1 Mass resists change in motion

12.1.2 Recall F = ma and solve related problems

12.1.3 Define and use linear momentum

12.1.4 Force as rate of change of momentum

12.1.5 State and apply Newton’s laws

12.1.6 Describe weight as effect of gravitational field

12.1.7 Weight of an object is mass × gravitational acceleration

12.2 Non-uniform Motion

12.2.1 Understand frictional and drag forces

12.2.2 Describe motion in uniform gravitational field with air resistance

12.2.3 Objects moving against resistive force may reach terminal velocity

12.3 Linear Momentum and its Conservation

12.3.1 State conservation of momentum

12.3.2 Apply conservation of momentum to solve problems

12.3.3 For elastic collision, kinetic energy and relative speed are conserved

12.3.4 Momentum is conserved, but some kinetic energy may change

13. Medical Physics

13.1 Production and Use of Ultrasound

13.1.1 Understand that a piezo-electric crystal changes shape when a p.d. is applied and generates an e.m.f

13.1.2 Understand how ultrasound waves are generated and detected by a piezoelectric transducer

13.1.3 Understand how ultrasound reflection at boundaries provides diagnostic information about internal st

13.1.4 Define specific acoustic impedance as Z = ρc

13.1.5 Use the equation IR / I₀ = (Z₁ – Z₂)² / (Z₁ + Z₂)² for the intensity reflection coefficient

13.2 Production and Use of X-rays

13.2.1 Explain that X-rays are produced by electron bombardment of a metal target and calculate the minimum

13.2.2 Understand the use of X-rays in imaging internal body structures and the term 'contrast' in X-ray im

13.2.3 Recall and use I = I₀e^(-μx) for the attenuation of X-rays in matter

13.2.4 Understand how computed tomography (CT) produces 3D images by combining multiple 2D X-ray images

13.3 PET Scanning

13.3.1 Understand that a tracer contains radioactive nuclei and is introduced into the body for imaging

13.3.2 Understand that β+ decay is used in positron emission tomography (PET)

13.3.3 Understand that annihilation occurs when a particle interacts with its antiparticle, conserving mass

13.3.4 Explain how gamma-ray photons from annihilation are detected to create an image of tracer concentrat

14. Waves

14.1 Progressive Waves

14.1.1 Describe wave motion in ropes, springs, and ripple tanks

14.1.2 Understand and use the terms displacement, amplitude, phase difference, period, frequency, wavelengt

14.1.3 Use time-base and y-gain on a cathode-ray oscilloscope (CRO) to determine frequency and amplitude

14.1.4 Derive and use v = f λ for the wave equation

14.1.5 Recall and use v = f λ

14.1.6 Understand energy transfer by a progressive wave

14.1.7 Recall and use intensity = power / area, intensity ∝ (amplitude)²

14.2 Transverse and Longitudinal Waves

14.2.1 Compare transverse and longitudinal waves

14.2.2 Analyze and interpret graphical representations of transverse and longitudinal waves

14.3 Doppler Effect for Sound Waves

14.3.1 Understand the change in frequency when a sound source moves relative to a stationary observer

14.3.2 Use the expression f₀ = fₛ(v / (v ± vₛ)) for the observed frequency

14.4 Electromagnetic Spectrum

14.4.1 State all electromagnetic waves are transverse waves traveling at the same speed in free space

14.4.2 Recall the range of wavelengths from radio waves to γ-rays

14.4.3 Recall that wavelengths 400–700 nm are visible to the human eye

14.5 Polarisation

14.5.1 Understand that polarisation is a phenomenon associated with transverse waves

14.5.2 Recall and use Malus's law (I = I₀ cos²θ) to calculate intensity of a plane-polarised wave after pas

15. The Mole

15.1 The Mole

15.1.1 Understand that amount of substance is an SI base quantity with the unit mol

15.1.2 Use molar quantities where one mole contains Avogadro's constant of particles

16. Equation of State

16.1 Ideal Gas Law

16.1.1 Understand that a gas obeying pV ∝ T is an ideal gas

16.1.2 Recall and use the equation pV = nRT for an ideal gas

16.1.3 Recall pV = NkT, where N = number of molecules and k is Boltzmann constant

16.1.4 Use the relationship k = R / NA

17. Kinetic Theory of Gases

17.1 Kinetic Theory

17.1.1 State the basic assumptions of the kinetic theory of gases

17.1.2 Explain pressure exerted by a gas due to molecular movement

17.1.3 Derive and use pV = (3/2)NmkT for pressure of a gas

17.1.4 Compare pV = (3/2)NmkT with pV = NkT to deduce average kinetic energy of a molecule

18. Particle Physics

18.1 Atoms, Nuclei and Radiation

18.1.1 Infer the existence and small size of the nucleus from α-particle scattering

18.1.2 Describe the nuclear atom model: protons, neutrons, and electrons

18.1.3 Distinguish between nucleon number and proton number

18.1.4 Understand isotopes as forms of the same element with different neutrons

18.1.5 Use the notation AZX for nuclides representation

18.1.6 Understand conservation of nucleon number and charge in nuclear processes

18.1.7 Describe the composition, mass, and charge of α-, β-, and γ-radiations

18.1.8 Understand antiparticles and positrons as antiparticles of electrons

18.1.9 State that (electron) antineutrinos are produced during β- decay and neutrinos during β+ decay

18.1.10 Represent α- and β-decay using radioactive decay equations

18.1.11 Use unified atomic mass unit (u) for mass

18.2 Fundamental Particles

18.2.1 Understand quarks as fundamental particles with six flavours

18.2.2 Understand hadrons as baryons (three quarks) or mesons (one quark and one antiquark)

18.2.3 Describe changes in quark composition during β- and β+ decay

18.2.4 Describe protons and neutrons as composed of quarks

18.2.5 Recall and use the charge of each quark and its respective antiquark

18.2.6 Recall electrons and neutrinos as fundamental particles (leptons)

19. Internal Energy

19.1 Internal Energy

19.1.1 Understand that internal energy is the sum of kinetic and potential energies of molecules in a syste

19.1.2 Relate rise in temperature to an increase in internal energy

20. Forces, Density and Pressure

20.1 Turning Effects of Forces

20.1.1 Weight acts at a single point: centre of gravity

20.1.2 Define and apply the moment of a force

20.1.3 Understand the concept of a couple

20.1.4 Define and apply torque of a couple

20.2 Equilibrium of Forces

20.2.1 State and apply the principle of moments

20.2.2 System in equilibrium has no resultant force or torque

20.2.3 Use a vector triangle to represent coplanar forces in equilibrium

20.3 Density and Pressure

20.3.1 Define and use density

20.3.2 Define and use pressure

20.3.3 Derive equation for hydrostatic pressure ∆p = ρg∆h

20.3.4 Use the equation ∆p = ρg∆h

20.3.5 Understand upthrust as the effect of hydrostatic pressure

20.3.6 Calculate upthrust using F = ρgV (Archimedes' principle)

21. Astronomy and Cosmology

21.1 Standard Candles

21.1.1 Understand luminosity as the total power radiated by a star

21.1.2 Recall and use the inverse square law F = L / (4πd²) for radiant flux intensity

21.1.3 Understand that an object with known luminosity is a standard candle

21.1.4 Use standard candles to determine distances to galaxies

21.2 Stellar Radii

21.2.1 Recall and use Wien’s displacement law λmax ∝ 1 / T to estimate the surface temperature of a star

21.2.2 Use Stefan–Boltzmann law L = 4πσr²T⁴

21.2.3 Use Wien’s law and Stefan–Boltzmann law to estimate the radius of a star

21.3 Hubble’s Law and Big Bang Theory

21.3.1 Understand redshift and the increase in wavelength of light from distant objects

21.3.2 Use ∆λ / λ = ∆f / f = v / c for redshift

21.3.3 Explain why redshift suggests the Universe is expanding

21.3.4 Recall and use Hubble’s law v = H₀d to explain the Big Bang theory

22. First Law of Thermodynamics

22.1 First Law

22.1.1 Recall and use W = p∆V for work done when the volume of a gas changes at constant pressure

22.1.2 Understand the difference between work done by a gas and work done on a gas

22.1.3 Recall and use the first law of thermodynamics: ∆U = q + W

23. Alternating Currents

23.1 Characteristics of Alternating Currents

23.1.1 Understand and use terms period, frequency, and peak value for alternating current or voltage

23.1.2 Use x = x₀ sin(ωt) for sinusoidal alternating current or voltage

23.1.3 Recall that the mean power in a resistive load is half the maximum power for sinusoidal current

23.1.4 Distinguish between root-mean-square (r.m.s.) and peak values and recall I₀r.m.s = I₀ / √2 and V₀r.m

23.2 Rectification and Smoothing

23.2.1 Distinguish graphically between half-wave and full-wave rectification

23.2.2 Explain the use of a single diode for half-wave rectification

23.2.3 Explain the use of four diodes (bridge rectifier) for full-wave rectification

23.2.4 Analyze the effect of a capacitor in smoothing, including the effect of capacitance and load resista

24. Superposition

24.1 Stationary Waves

24.1.1 Explain and use the principle of superposition

24.1.2 Understand experiments demonstrating stationary waves using microwaves, stretched strings, and air c

24.1.3 Explain the formation of stationary waves using graphical methods and identify nodes and antinodes

24.1.4 Determine wavelength from the positions of nodes or antinodes

24.2 Diffraction

24.2.1 Explain diffraction and show understanding of related experiments

24.2.2 Understand the effect of gap width relative to wavelength in diffraction experiments

24.3 Interference

24.3.1 Understand the terms interference and coherence

24.3.2 Demonstrate two-source interference using water waves, sound, light, and microwaves

24.3.3 Understand the conditions required for two-source interference fringes

24.3.4 Recall and use λ = ax / D for double-slit interference with light

24.4 Diffraction Grating

24.4.1 Recall and use d sin θ = nλ for diffraction grating calculations

24.4.2 Describe the use of a diffraction grating to determine the wavelength of light

25. Simple Harmonic Oscillations

25.1 Simple Harmonic Motion

25.1.1 Understand and use terms displacement, amplitude, period, frequency, angular frequency, and phase di

25.1.2 Understand that simple harmonic motion occurs when acceleration is proportional to displacement from

25.1.3 Use a = -ω²x and recall x = x₀ sin(ωt) as the solution

25.1.4 Use v = v₀ cos(ωt) and v = ±ω√(x₀² - x²) for velocity

26. Energy in Simple Harmonic Motion

26.1 Energy in SHM

26.1.1 Describe the interchange between kinetic and potential energy during SHM

26.1.2 Recall and use E = ½mω²x₀² for the total energy of a system undergoing SHM

27. Quantum Physics

27.1 Energy and Momentum of a Photon

27.1.1 Understand that electromagnetic radiation has a particulate nature

27.1.2 Recall and use E = hf for the energy of a photon

27.1.3 Use the electronvolt (eV) as a unit of energy

27.1.4 Understand that a photon has momentum and use p = E / c for photon momentum

27.2 Photoelectric Effect

27.2.1 Understand that photoelectrons are emitted from a metal surface when illuminated by electromagnetic

27.2.2 Understand and use the terms threshold frequency and threshold wavelength

27.2.3 Explain photoelectric emission in terms of photon energy and work function

27.2.4 Recall and use hf = Φ + ½mv² for the maximum kinetic energy of photoelectrons

27.2.5 Explain why the maximum kinetic energy of photoelectrons is independent of intensity, while current

27.3 Wave-Particle Duality

27.3.1 Understand that the photoelectric effect shows the particulate nature of light, while diffraction sh

27.3.2 Describe and interpret electron diffraction as evidence for the wave nature of particles

27.3.3 Understand the de Broglie wavelength as the wavelength associated with a moving particle

27.3.4 Recall and use λ = h / p for de Broglie wavelength

27.4 Energy Levels in Atoms and Line Spectra

27.4.1 Understand discrete electron energy levels in atoms (e.g., atomic hydrogen)

27.4.2 Understand the appearance and formation of emission and absorption line spectra

27.4.3 Recall and use hf = E₁ – E₂ for the energy difference between electron energy levels

28. Damped and Forced Oscillations, Resonance

28.1 Damped Oscillations

28.1.1 Understand that damping occurs due to resistive forces

28.1.2 Understand the types of damping: light, critical, and heavy damping

28.2 Resonance

28.2.1 Understand that resonance occurs when an oscillating system is forced to oscillate at its natural fr

29. Work, Energy and Power

29.1 Energy Conservation

29.1.1 Understand the concept of work, and recall W = F × s

29.1.2 Apply the principle of conservation of energy

29.1.3 Understand efficiency as useful energy output / total energy input

29.1.4 Use efficiency concept to solve problems

29.1.5 Define power as work done per unit time

29.1.6 Solve problems using P = W / t

29.1.7 Derive P = Fv and solve problems

29.2 Gravitational Potential Energy and Kinetic Energy

29.2.1 Derive ∆EP = mg∆h for gravitational potential energy changes

29.2.2 Recall and use ∆EP = mg∆h for gravitational potential energy changes

29.2.3 Derive EK = ½mv² for kinetic energy

29.2.4 Recall and use EK = ½mv² for kinetic energy

30. Electric Fields

30.1 Electric Fields and Field Lines

30.1.1 Understand that an electric field is a field of force and define it as force per unit positive charg

30.1.2 Represent an electric field using field lines

30.2 Uniform Electric Fields

30.2.1 Recall and use E = ∆V / ∆d to calculate electric field strength between charged parallel plates

30.2.2 Describe the effect of a uniform electric field on the motion of charged particles

30.3 Electric Force Between Point Charges

30.3.1 Understand that, for a point outside a spherical conductor, the charge may be considered a point mas

30.3.2 Recall and use Coulomb’s law F = Q₁Q₂ / (4πε₀r²) for the force between two point charges

30.4 Electric Field of a Point Charge

30.4.1 Recall and use E = Q / (4πε₀r²) for the electric field strength due to a point charge

30.5 Electric Potential

30.5.1 Define electric potential as work done per unit positive charge in bringing a test charge from infin

30.5.2 Recall and use V = Q / (4πε₀r) for electric potential due to a point charge

30.5.3 Understand how electric potential leads to electric potential energy of two point charges and use EP

31. Physical Quantities and Units

31.1 Physical Quantities

31.1.1 Physical quantities consist of magnitude and unit

31.1.2 Estimate physical quantities from the syllabus

31.2 SI Units

31.2.1 SI base units: mass, length, time, current, temperature

31.2.2 Express derived units from SI base units

31.2.3 Check homogeneity of physical equations

31.2.4 Use prefixes (pico, nano, micro, kilo, etc.)

31.3 Errors and Uncertainties

31.3.1 Understand systematic and random errors

31.3.2 Assess uncertainty in derived quantities

31.4 uniform Electric Fields

31.4.1 Distinguish between precision and accuracy

31.5 Scalars and Vectors

31.5.1 Difference between scalar and vector quantities

31.5.2 Add and subtract coplanar vectors

31.5.3 Represent a vector as components

32. Motion in a Circle

32.1 Centripetal Acceleration

32.1.1 Understand centripetal acceleration and its role in circular motion

32.1.2 Recall and use a = rω² and a = v² / r

32.1.3 Recall and use F = mrω² and F = mv² / r

32.1.4 Understand force causing centripetal acceleration is always perpendicular to motion

32.2 Kinematics of Uniform Circular Motion

32.2.1 Recall and use ω = 2π / T and v = rω

32.2.2 Understand and use angular speed

32.2.3 Define and express angular displacement in radians

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Understand that Amount of Substance is an SI Base Quantity with the Unit Mol

Introduction